Valence electrons are the outermost electrons of an atom and play a crucial role in determining its chemical properties and reactivity. They are involved in forming chemical bonds, such as covalent and ionic bonds, and dictate how atoms interact with each other in molecules and compounds.
An electron shell is a grouping of electrons surrounding the nucleus of an atom, which determines the atom's chemical properties and reactivity. These shells are divided into subshells and orbitals, and their arrangement follows the principles of quantum mechanics and the Pauli exclusion principle.